Coordination Chemistry

This series of textbooks reflects the breadth of modern research in inorganic chemistry and fulfils the need for advanced texts. The series will cover the whole range of inorganic and physical chemistry, solid state chemistry, coordination chemistry, organometallic chemistry, main group chemistry and bioinorganic chemistry. 100 years after the formulation of the coordination theory by Alfred Werner, stereochemical considerations are again at the centre of interest in the development of metal complexes. Reflecting this renewed interest, Stereochemistry of Coordination Compounds explains the modern aspects of this area of chemistry, firstly by introducing the stereochemistry of various coordination geometries. The later chapters go on to address applications in the field of polynuclear species and stereochemical aspects of reactions, including enantioselective catalysis. Stereochemistry of Coordination Compounds provides: A systematic introduction to the structures of molecular species with atoms of various coordination number, focusing on the most important octahedral caseA presentation of the principles that are applied to produce molecular helices, chains and knotsAn account of the historical background of the stereochemistry of coordination compoundsAn introduction to the stereochemical nomenclature of coordination compoundsElectronic figure files that are available on the InternetStereochemistry of Coordination Compounds is essential reading for undergraduates, post-graduate students and lecturers specializing in coordination chemistry in inorganic and bioinorganic chemistry. The cover shows a random pattern stereogram of an octahedron, designed by Oliver Fuhrer, Lupsingen,Switzerland. In the text, extensive use is made of the ability of computers to display 3D pairs of molecules. The grey scale figure that was used to create the random pattern stereogram is shown below.

The most comprehensive guide to infrared and Raman spectra of inorganic and coordination compounds now fully revised and updated Infrared and Raman Spectra of Inorganic and Coordination Compounds has always provided fundamental theories of vibrational spectroscopy in a condensed form and their applications to inorganic and coordination compounds. The Fifth Edition continues to cover these theories and applications, which have been updated by adding many new topics, figures, tables, and references. Part A of this two-volume work describes basic theories of normal vibrations including the method of normal coordinate analysis, resonance Raman spectroscopy, and vibrational analysis of crystals in clear and precise terms, and applies them to relatively simple inorganic compounds while leaving the applications to larger and more complex systems to Part B. This new edition Incorporates new topics such as the correlation method, lattice vibrations, ceramic superconductors, and carbon clusters such as buckminsterfullerene Offers numerous references to the recent research in the field Reviews significant new literature on the subject Provides many infrared and Raman spectral charts of typical compounds Features 116 illustrations Contains appendices consisting of tables, charts, and supplementary information Used independently or in combination with Part B, this is an excellent textbook for graduate-level course work, and the most comprehensive reference book available for researchers in the fields of vibrational spectroscopy, inorganic chemistry, coordination chemistry, organometallic chemistry, and bioinorganic chemistry.

Coordination number - In chemistry, the coordination number is the sum of the total number of neighbors of a central atom in a chemical compound and the number of lone pairs on it. In methane the coordination number for the carbon atom is 4.

Octahedral molecular geometry - The octahedral molecular geometry is a part of coordination chemistry and describes a molecular geometry in which atoms or ligands are arranged around a central atom with 4 of them in the same plane as the central atom at the corners of a square (basal positions) and two more at either side of the plane forming a straight line with the central atom (the apical postions). The central atom is often a transition metal.

Laporte rule - The Laporte rule in coordination chemistry states that when the transition is

Î backbonding - Ï€ backbonding, also called Ï€ backdonation, is a concept from chemistry, that refers to the flow of electrons from an atomic orbital on one atom to a Ï€ anti-bonding orbital that belongs to other atoms. It is especially common in the coordination of multi-atomic ligands to metal centres, where electrons from the metal flow towards the bond between the ligand atoms, thereby relieving the metal from excess negative charge and allowing it to bond with the ligands.

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